Deuterium hyperfine structure measurements and theory for CD/sub 3/Br
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:5840207
Hyperfine structure on the J = 1..-->..0, F/sub 1/ = 3/2 transitions in CH/sub 3/ /sup 79/Br, CH/sub 3/ /sup 81/Br, and CD/sub 3/ /sup 79/Br was measured with one-cavity and two-cavity beam maser spectrometers. The resolution for the measurements was approximately 2 kHz and most hyperfine structure components were completely resolved. Deuterium quadrupole coupling eQq/sub z/z = 178.5 +- 3 khz along the C--D bond and other parameters were obtained. In the theory section, formulas for the hyperfine interaction strengths with three equivalent spins are presented and reviewed. Deuterium quadrupole coupling in other C--D bond systems is discussed.
- Research Organization:
- Department of Chemistry, University of Arizona, Tucson, Arizona 85721
- OSTI ID:
- 5840207
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 76:4; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
BROMINATED ALIPHATIC HYDROCARBONS
DEUTERIUM
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
ISOTOPES
LIGHT NUCLEI
MICROWAVE SPECTRA
NUCLEI
ODD-ODD NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ROTATIONAL STATES
SPECTRA
STABLE ISOTOPES
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
BROMINATED ALIPHATIC HYDROCARBONS
DEUTERIUM
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
ISOTOPES
LIGHT NUCLEI
MICROWAVE SPECTRA
NUCLEI
ODD-ODD NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ROTATIONAL STATES
SPECTRA
STABLE ISOTOPES