Vibrational spectroscopy and intramolecular relaxation of benzene

Journal Article · Mon Nov 15 04:00:00 EST 1993 · Journal of Chemical Physics; (United States)

DOI:https://doi.org/10.1063/1.465715· OSTI ID:5838202

Iachello, F ^[1]; Oss, S ^[2]

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1. Center for Theoretical Physics, Sloane Laboratory, Yale University, New Haven, Connecticut 06511 (United States)
2. Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States)

By making use of Lie algebraic methods, we construct the complete vibrational spectrum of benzene. We use this construction to study the process of intramolecular vibrational energy relaxation in the first and second overtone of the CH stretching mode.

• DOE Contract Number: FG02-91ER40608
• OSTI ID: 5838202
• Journal Information: Journal of Chemical Physics; (United States), Journal Name: Journal of Chemical Physics; (United States) Vol. 99:10; ISSN JCPSA6; ISSN 0021-9606
• Country of Publication: United States
• Language: English

Related Subjects

664100* -- Theory of Electronic Structure of Atoms & Molecules-- (1992-)
74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
BENZENE
ENERGY LEVELS
EXCITED STATES
HARMONICS
HYDROCARBONS
INFRARED SPECTRA
MATHEMATICAL MODELS
MOLECULAR MODELS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
OSCILLATIONS
SPECTRA
SYMMETRY
VIBRATIONAL STATES