Semiclassical description of hyperfine interaction in calculating chemically induced dynamic nuclear polarization in weak magnetic fields

Journal Article · Tue Sep 01 00:00:00 EDT 1987 · Theor. Exp. Chem. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00534581· OSTI ID:5837737

Purtov, P A; Salikhov, K M

Semiclassical HFI description is applicable to calculating the integral CIDNP effect in weak fields. The HFI has been calculated for radicals with sufficiently numerous magnetically equivalent nuclei (n greater than or equal to 5) in satisfactory agreement with CIDNP calculations based on quantum-mechanical description of radical-pair spin dynamics.

• OSTI ID: 5837737
• Journal Information: Theor. Exp. Chem. (Engl. Transl.); (United States), Vol. 23:2; Other Information: Translated from Teor. Eksp. Khim.; 23: No. 2, 204-207(Mar-Apr 1987)
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
RADICALS
ATOMIC MODELS
HYPERFINE STRUCTURE
MAGNETIC FIELDS
SPIN ORIENTATION
ELECTRON SPIN RESONANCE
LARMOR RADIUS
NUCLEAR MAGNETIC MOMENTS
NUCLEI
PERTURBATION THEORY
QUANTUM MECHANICS
RECOMBINATION
SEMICLASSICAL APPROXIMATION
MAGNETIC MOMENTS
MAGNETIC RESONANCE
MATHEMATICAL MODELS
MECHANICS
NUCLEAR PROPERTIES
ORIENTATION
RESONANCE
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory