Mechanisms of oxidation of phenol and cyclohexene by an oxo complex of ruthenium(IV)
Journal Article
·
· Inorg. Chem.; (United States)
The mechanism of the oxidation of phenols and cyclohexene catalyzed by the ruthenium(IV)-oxo complexes has been studied using a variety of techniques, e.g. kinetics, /sup 18/O labeling, H/D kinetic isotope effects, and the appearance of reaction intermediates. Preliminary results of a series of studies that illustrate the mechanistic versatility of the Ru(IV)=O/sup 2+/ oxidant in this system are presented. 22 refs.
- Research Organization:
- Univ. of North Carolina, Chapel Hill (USA)
- OSTI ID:
- 5835581
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:1; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Ruthenium(IV)-oxo complexes: the novel utilization of tertiary pnictogen ligands
Aerobic oxidation of cyclohexene with a phosphine-ruthenium(II)-aquo catalyst
(oxo)(phosphine)ruthenium(IV) complexes: oxygen atom transfer in the oxidation of olefins, sulfides, sulfoxides, and free phosphines
Journal Article
·
Tue Mar 01 23:00:00 EST 1988
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:7256247
Aerobic oxidation of cyclohexene with a phosphine-ruthenium(II)-aquo catalyst
Journal Article
·
Tue Dec 29 23:00:00 EST 1987
· Inorg. Chem.; (United States)
·
OSTI ID:5900224
(oxo)(phosphine)ruthenium(IV) complexes: oxygen atom transfer in the oxidation of olefins, sulfides, sulfoxides, and free phosphines
Journal Article
·
Wed Nov 30 23:00:00 EST 1988
· J. Coord. Chem.; (United States)
·
OSTI ID:5830811
Related Subjects
090110* -- Hydrocarbon Fuels-- Properties-- (1979-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKENES
AROMATICS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
DEUTERIUM
ELEMENTS
EVEN-EVEN NUCLEI
HYDROCARBONS
HYDROGEN
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
ISOTOPE EFFECTS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
OXIDATION
OXYGEN 18
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
PHENOL
PHENOLS
RUTHENIUM COMPLEXES
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKENES
AROMATICS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
DEUTERIUM
ELEMENTS
EVEN-EVEN NUCLEI
HYDROCARBONS
HYDROGEN
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
ISOTOPE EFFECTS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
OXIDATION
OXYGEN 18
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
PHENOL
PHENOLS
RUTHENIUM COMPLEXES
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES