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Nature of the electronic interactions of the no group with the metal atom and its charge state in substituted nitroso complexes of Ru according to x-ray spectra

Journal Article · · J. Struct. Chem. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00752050· OSTI ID:5830854
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An investigation of the electronic structure of nitroso complexes of ruthenium of the types (RuL/sub 5/NO) and (Ru(NH/sub 3/)/sub 4/NOX), where L = CN/sup /minus//, Cl/sup /minus//, Br/sup /minus//, I/sup /minus//, and X = Cl/sup /minus//, Br/sup /minus//, I/sup /minus//, SCN/sup /minus//, has been carried out. It has been shown that the spectra of the oxygen atom in the NO ligand make it possible to investigate the manifestations of the /sigma/-donor and /pi/-acceptor properties of the nitroso group, that they are sensitive to the geometric position of the Ru-N-O bond, and that they permit the determination of the formal charge of the NO group as a function of the ligand L in ruthenium complexes.

OSTI ID:
5830854
Journal Information:
J. Struct. Chem. (Engl. Transl.); (United States), Journal Name: J. Struct. Chem. (Engl. Transl.); (United States) Vol. 28:5; ISSN JSTCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ANTITHYROID DRUGS
BINDING ENERGY
BROMIDES
BROMINE COMPOUNDS
CARBONIC ACID DERIVATIVES
CHARGE STATE
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
CONFIGURATION INTERACTION
CYANIDES
DRUGS
ELECTRON DENSITY
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
FERMIONS
HALIDES
HALOGEN COMPOUNDS
HORMONE ANTAGONISTS
IODIDES
IODINE COMPOUNDS
LEPTONS
LIGANDS
MECHANICS
MOLECULAR STRUCTURE
NITROSO COMPOUNDS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN
QUANTUM MECHANICS
REFRACTORY METAL COMPOUNDS
RUTHENIUM BROMIDES
RUTHENIUM CHLORIDES
RUTHENIUM COMPLEXES
RUTHENIUM COMPOUNDS
SPECTRA
SPECTROSCOPY
THIOCYANATES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
VALENCE
X-RAY SPECTRA
X-RAY SPECTROSCOPY