Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide

Journal Article · Wed Feb 05 00:00:00 EST 1986 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00263a008· OSTI ID:5826848

Kojima, F; Aida, T; Inoue, S

Carbon dioxide is trapped by (5,10,15,20-tetraphenylporphinato) aluminum acetate in the presence of a secondary amine in the form of an aluminum carbamate on the opposite side to the acetate group with respect to the porphyrin plane. Carbon dioxide thus trapped by aluminum porphyrin is activated enough to undergo a catalytic reaction involving secondary amine and epoxide to afford dialkylcarbamic ester under atmospheric pressure at room temperature. 15 references, 2 figures, 2 tables.

• Research Organization: Univ. of Tokyo, Japan
• OSTI ID: 5826848
• Journal Information: J. Am. Chem. Soc.; (United States), Vol. 108:3
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
CATALYTIC EFFECTS
ALUMINIUM
AMINES
CHEMICAL REACTIONS
CARBAMIC ACID ESTERS
CHEMICAL PREPARATION
CARBON DIOXIDE
CARBON DIOXIDE FIXATION
EFFICIENCY
EPOXIDES
PORPHYRINS
ATMOSPHERIC PRESSURE
CATALYSIS
CATALYSTS
EXPERIMENTAL DATA
MEDIUM TEMPERATURE
NMR SPECTRA
CARBON COMPOUNDS
CARBON OXIDES
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CHALCOGENIDES
DATA
ELEMENTS
ESTERS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
INFORMATION
METALS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SPECTRA
SYNTHESIS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)