Transformation of monoclinic CfBr/sub 3/ to orthorhombic CfBr/sub 3/ by the application of pressure
Journal Article
·
· Inorg. Chem.; (United States)
A new synthetic route to the orthorhombic form of CfBr/sub 3/ is reported. A few micrograms of monoclinic CfBr/sub 3/ is loaded and studied in a triangular-shaped diamond anvil pressure cell similar to that reported by Merrill and Bassett. Based on analysis of the absorption spectra obtained from the CfBr/sub 3/ sample at several pressures up to 3.4 GPa, it is concluded that the structural transformation of monoclinic CfBr/sub 3/ to orthorhombic CfBr/sub 3/ takes place between 1.7 and 3.4 GPa. 10 references, 1 figure.
- Research Organization:
- Univ. of Tennessee, Knoxville
- DOE Contract Number:
- AS05-76ER04447
- OSTI ID:
- 5817064
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 24:16; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ABSORPTION SPECTROSCOPY
ACTINIDE COMPOUNDS
CALIFORNIUM COMPOUNDS
CALIFORNIUM FLUORIDES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
MONOCLINIC LATTICES
NUMERICAL DATA
ORTHORHOMBIC LATTICES
PRESSURE DEPENDENCE
SPECTROSCOPY
TRANSPLUTONIUM COMPOUNDS
TRANSURANIUM COMPOUNDS
VERY HIGH PRESSURE
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ABSORPTION SPECTROSCOPY
ACTINIDE COMPOUNDS
CALIFORNIUM COMPOUNDS
CALIFORNIUM FLUORIDES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
MONOCLINIC LATTICES
NUMERICAL DATA
ORTHORHOMBIC LATTICES
PRESSURE DEPENDENCE
SPECTROSCOPY
TRANSPLUTONIUM COMPOUNDS
TRANSURANIUM COMPOUNDS
VERY HIGH PRESSURE