Photochemical carbonylation of benzene by iridium(I) and rhodium(I) square-planar complexes
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Photolysis of RhCl(CO)(PPh/sub 3/)/sub 2/ and RhH(CO)(PPh/sub 3/)/sub 2/ complexes under long-term continuous irradiation leads to significant and new overall reaction chemistry. This chemistry, which is only observed upon photolysis, involves arene C-H functionalization and, in particular, the carbonylation of benzene to benzaldehyde. This observed C-H bond functionalization contrasts with the known oxidative carbonylation of arenes using Pd/sup 2 +/ in that no prior activation of the benzene ring is needed. 11 references, 1 figure.
- Research Organization:
- Univ. of Rochester, NY
- OSTI ID:
- 5813796
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 108:3; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Photochemical carbonylation of benzene by iridium(I) and rhodium(I) square-planar complexes
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
DECOMPOSITION
EXPERIMENTAL DATA
INFORMATION
MAGNETIC RESONANCE
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
RESONANCE
RHODIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS
400600* -- Radiation Chemistry
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
DECOMPOSITION
EXPERIMENTAL DATA
INFORMATION
MAGNETIC RESONANCE
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
RESONANCE
RHODIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS