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U.S. Department of Energy
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Environmentally-induced passivity of aluminum alloys and aluminum metal-matrix composites. Final report, 1 Oct 87-30 Sep 90

Technical Report ·
OSTI ID:5812913

This final report presents a summary of the work performed under Contract No. N00014-88-K-0034. One of the goals of the research carried out was to develop corrosion protection methods for Al-based materials which can replace the presently used chromate conversion coatings with modified surface layers of equal or even better resistance to localized corrosion. The past work first evaluated the use of rare earth metal chlorides (REMC) for the passivation of Al alloys and Al/SiC by a simple immersion treatment. Very corrosion resistant surfaces have been obtained in this manner which did not show any localized corrosion during exposure to aerated NaCl for periods up to 60 days. In an attempt to shorten the passivation time, a passivation treatment in solutions of CeCl{sub 3}, and Ce(NO{sub 3}){sub 3} has been developed. Very corrosion resistant surfaces have been produced in a process in which immersion in CeCl{sub 3} and Ce(NO{sub 3}){sub 3} was followed by an electrochemical treatment in Na{sub 2}MoO{sub 4}.

Research Organization:
University of Southern California, Los Angeles, CA (USA). Dept. of Materials Science and Engineering
OSTI ID:
5812913
Report Number(s):
AD-A-231350/0/XAB; CNN: N00014-88-K-0034
Country of Publication:
United States
Language:
English