Resistance of fluorine-hydrogen mixtures to chain self-ignition

Journal Article · Mon Sep 01 04:00:00 EDT 1980 · Combust., Explos. Shock Waves (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00740194· OSTI ID:5807945

Vasilev, G K; Makarov, E F; Chernyshev, Iu A

Data on the mechanism and rate constants of chemical reactions and vibrational relaxation processes in the F2 + H2 system lead to the conclusion that a small addition of HF (0.01 to 0.001) in the original mixture can play a significant role in the stabilization of the mixture. This paper presents a theoretical analysis of the behavior of F2 + H2 mixtures upon passing the upper limit of chain self-ignition, taking into account the HF present as an impurity and also formed during the reaction.

• OSTI ID: 5807945
• Journal Information: Combust., Explos. Shock Waves (Engl. Transl.); (United States), Journal Name: Combust., Explos. Shock Waves (Engl. Transl.); (United States) Vol. 16; ISSN CESWA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
BINARY MIXTURES
CHEMICAL REACTION KINETICS
COLLISIONS
DISPERSIONS
ELEMENTS
FLUORINE
HALOGENS
HYDROGEN
IGNITION
IMPURITIES
KINETICS
MIXTURES
MOLECULE COLLISIONS
NONMETALS
REACTION KINETICS
RELAXATION
SPECTRA
TEMPERATURE DEPENDENCE