Liquid phase oxidation studies; Chemical ionization of alkyl ketones in an ion trap mass spectrometer
Journal Article
·
· Fuel Science and Technology International; (USA)
- Geo-Centers, Inc., Ft. Washington, MD (US)
- Naval Research Lab., Navy Technology Center for Safety and Survivability Fuels Section, Washington, DC (US)
The oxygen or hydroperoxide oxidation of various organo-sulfur compounds in both model and real fuels is an area that is presently under renewed investigation. Sulfur compounds of interest include thiols and disulfides in particular. Autoxidation reactions produce besides the expected sulfur oxidation products: sulfoxides, sulfones, thiosulfonates and sulfonic acids, small amounts of hydrocarbon oxygenates from the model fuel, dodecane. It is noted that the mass spectra of the oxygen species gave results that were instrument dependent. The results from an ion trap detector are quite different when compared to a dodecapole mass spectrometer.
- OSTI ID:
- 5805244
- Journal Information:
- Fuel Science and Technology International; (USA), Journal Name: Fuel Science and Technology International; (USA) Vol. 8:9; ISSN FSCTE; ISSN 0884-3759
- Country of Publication:
- United States
- Language:
- English
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