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Inter-relation of corrosion and fouling for metals in sea water

Journal Article · · Mater. Performance; (United States)
OSTI ID:5799613
Carbon steel, aluminum, and copper alloys submerged at the Inco Wrightsville Beach, NC, test station were evaluated by International Nickel Co., Inc., for their ability to resist sea marine fouling for up to 5 years. The study demonstrated that the fouling properties are influenced by the corrosion characteristics of the alloys, which can be placed into one of three classes: highly corrodible metals, passive metals, and toxic film-forming metals. Highly corrodible alloys such as steel will foul; the fouling can be removed easily with the loose corrosion product, sloughing off at intervals during exposure. However, the fouling on passive alloys is tightly adherent and restricts the diffusion of oxygen to the metal surface. The only effect on corrosion occurs when the material is sensitive to oxygen-concentration cells, causing crevice corrosion beneath the fouling organisms. The copper-base alloys possess fouling resistance because of the formation of an adherent cuprous oxide corrosion product that is toxic to the organisms. Materials such as beryllium and lead, which are expected to form toxic films, do not remain free of fouling.
OSTI ID:
5799613
Journal Information:
Mater. Performance; (United States), Journal Name: Mater. Performance; (United States) Vol. 15; ISSN MTPFB
Country of Publication:
United States
Language:
English