Correlation of core electron binding energies with charge distributions for compounds of carbon, silicon, and germanium

Journal Article · Tue Jan 01 00:00:00 EST 1974 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic50135a038· OSTI ID:5798105

Perry, W B; Jolly, W L

Core electron binding energies for analogous compounds of carbon, silicon, and germanium have been measured by X-ray photoelectron spectroscopy in the gas phase. The chemical shifts have been correlated by the electrostatic potential equation using charge distributions from extended Huckel theory, CNDO/2, and an electronegativity equalization method. The data can be rationalized without any consideration p..pi -->..d..pi.. or p(pi)..-->..d(pi) in the silicon and germanium compounds.

• Research Organization: Univ. of California, Berkeley
• OSTI ID: 5798105
• Journal Information: Inorg. Chem.; (United States), Vol. 13:5
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CALCULATION METHODS
CORRELATIONS
CARBON COMPOUNDS
BINDING ENERGY
PHOTOELECTRON SPECTROSCOPY
CHARGE DISTRIBUTION
GERMANIUM COMPOUNDS
SILICON COMPOUNDS
CHEMICAL SHIFT
ELECTRONIC STRUCTURE
EXPERIMENTAL DATA
GASES
ISOLATED VALUES
DATA
DATA FORMS
ELECTRON SPECTROSCOPY
ENERGY
FLUIDS
INFORMATION
NUMERICAL DATA
SPECTROSCOPY
400201* - Chemical & Physicochemical Properties