Crystal and molecular structure of a new organic metal,. beta. -(BEDT-TTF)/sub 2/ICl/sub 2/
Journal Article
·
· Dokl. Chem. (Engl. Transl.); (United States)
OSTI ID:5797412
The discovery of superconductivity in ..beta..-(BEDT-TTF)/sub 2/I/sub 3/, where BEDT-ITF (or ET) is bis(ethylenedithio)tetrahydrofulvalene with T/sub S/ = 1.5-7.5 K, which is unsurpassed among the reported organic superconductors, has stimulated the search for new superconductors among ET complexes. Great interest is found in the preparation of ET salts with linear anions which are analogs of I/sub 3//sup -/ such as I/sub 2/Br/sup -/, IBr/sub 2//sup -/, ICl/sub 2//sup -/, Br/sub 3//sup -/, and MX/sub 2/ where M is a metal and X is a halide. ..beta..-(ET)/sub 2/I/sub 2/Br, ..cap alpha..- and ..beta..-(ET)/sub 2/IBr/sub 2/, and (ET)/sub 2/AuI/sub 2/ have now been synthesized and studied. They report the synthesis, structure, and properties of a new complex, ..beta..-(ET)/sub 2/ICl/sub 2/.
- Research Organization:
- Institute of Chemical Physics, Moscow, USSR
- OSTI ID:
- 5797412
- Journal Information:
- Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 292:4-6; ISSN DKCHA
- Country of Publication:
- United States
- Language:
- English
Similar Records
New cation-anion interaction motifs, electronic band structure, and electrical behavior in. beta. -(ET)/sup 2/X salts (X = ICl/sub 2/. pi. and BrICl/sup -/). [. beta. -bis(ethylenedithio)tetrathiafulvalene]
beta. -(BEDT-TTF)/sub 2/-AuCl/sub 4/: Importance of hydrogen--anion interactions in a descructive phase transition observed at low temperatures
Recent progress in BEDT-TTF based synthetic metals
Journal Article
·
Tue Feb 18 23:00:00 EST 1986
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5896844
beta. -(BEDT-TTF)/sub 2/-AuCl/sub 4/: Importance of hydrogen--anion interactions in a descructive phase transition observed at low temperatures
Technical Report
·
Sat Dec 31 23:00:00 EST 1988
·
OSTI ID:6417087
Recent progress in BEDT-TTF based synthetic metals
Conference
·
Mon Aug 01 00:00:00 EDT 1988
· Phosphorus and Sulfur and the Related Elements; (UK)
·
OSTI ID:5210863
Related Subjects
36 MATERIALS SCIENCE
360602* -- Other Materials-- Structure & Phase Studies
360603 -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
AROMATICS
BOND ANGLE
BOND LENGTHS
CHLORINATED AROMATIC HYDROCARBONS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HALOGENATED AROMATIC HYDROCARBONS
IODINATED AROMATIC HYDROCARBONS
LATTICE PARAMETERS
LENGTH
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
PHYSICAL PROPERTIES
SCATTERING
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
SUPERCONDUCTIVITY
X-RAY DIFFRACTION
360602* -- Other Materials-- Structure & Phase Studies
360603 -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
AROMATICS
BOND ANGLE
BOND LENGTHS
CHLORINATED AROMATIC HYDROCARBONS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HALOGENATED AROMATIC HYDROCARBONS
IODINATED AROMATIC HYDROCARBONS
LATTICE PARAMETERS
LENGTH
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
PHYSICAL PROPERTIES
SCATTERING
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
SUPERCONDUCTIVITY
X-RAY DIFFRACTION