Reactions of derivatives of phosphorus thio acids containing S-H, S-Si, and S-Cl bonds with alkenyl-silanes and -stannanes
The ..pi.. and sigma centers of alkenyl-silanes and -stannanes can participate in reactions with derivatives of phosphorus thio acids containing S-H and S-Cl bonds. Change in the structure of the alkenyl group and in the nature of the metal in the substrate influences the character of the substances formed substantially. The difference in the chemical behaviors of dialkoxyoxophosphoranesulfenyl chlorides and benzenesulfenyl chloride in reactions with unsaturated organo-silicon and -tin compounds results from the formation of structurally different intermediate compounds in the electrophilic attack of the sulfenyl chloride on the double bond. S-(Trimethylsilyl) esters of phosphorus dithio acids are able to react with vinyl- and allyl-stannanes by a substitution scheme with the formation of the corresponding alkenyl-stannanes and S-stannyl phosphorodithioates.
- Research Organization:
- V. I. Ul'yanov-Lenin Kazan' State Univ., USSR
- OSTI ID:
- 5795669
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:10; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
CARBON 13
CARBON ISOTOPES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED AROMATIC HYDROCARBONS
COMPLEXES
COUPLING
COUPLING CONSTANTS
DITHIOLS
ESTERS
EVEN-ODD NUCLEI
HALOGENATED AROMATIC HYDROCARBONS
HYDRIDES
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SILICON COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHONIC ACID ESTERS
PHOSPHONIC ACIDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
REACTION KINETICS
REAGENTS
SILANES
SILICON COMPLEXES
SILICON COMPOUNDS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
THIOLS
TIN COMPLEXES