Synthesis and some reactions of phosphorylated derivatives of s-triazine

Journal Article · Tue May 20 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5793803

Zimin, M G; Fomakhin, E V; Islamov, R G; Pudovik, A N

Tris(dialkoxyphosphinothioylthio)-s-triazines show no tendency to undergo tautomeric processes. When heated, they are converted into 0,0-dialkyl phosphorisothiocyanatidothioates. In the treatment of tris(dialkoxyphosphinothioylthio)-s-triazines with aniline the replacement of the dialkoxyphosphinothioylthio groups occurs with the formation of (dianilino-s-triazinyl)-phenylammonium 0,0-dialkyl phosphorodithioates. The reactions with 0,0-dialkyl hydrogen phosphorodithioates lead to the formation of tetraalkyl trithiopyrophosphoates. Tris(dialkoxyphosphinylthio)-s-triazines are capable of tautomerism, arising from the S in equilibrium N migration of phosphoryl groups. The tautomerization goes intermolecularly and stagewise. Tris(dialkoxyphosphinylthio)-s-triazines undergo hydrolysis under mild conditions, leading finally to the formation of 1-(dialkoxyphosphinyl)tetrahydro-4,6-dithioxo-s-traizin-2(1H)-ones.

• Research Organization: V.I. Ul'yanov-Lenin Kazan' State Univ., USSR
• OSTI ID: 5793803
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:12; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AZINES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
DITHIOLS
DOUBLE RESONANCE METHODS
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
REAGENTS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TEMPERATURE DEPENDENCE
THIOLS
TRIAZINES