Magnetic and Moessbauer studies on rare-earth-containing Heusler alloys Pd/sub 2/RSn (R = Tb--Yb)

Journal Article · Sat Jun 01 00:00:00 EDT 1985 · Phys. Rev. B: Condens. Matter; (United States)

DOI:https://doi.org/10.1103/PhysRevB.31.6971· OSTI ID:5790745

Malik, S K; Umarji, A M; Shenoy, G K

Magnetic susceptibility and /sup 119/Sn Moessbauer studies have been carried out on a new series of rare-earth-containing Heusler alloys having the formula Pd/sub 2/RSn (R = Tb--Yb). The Tm and Yb compounds in this series along with Lu, Sc, and Y compounds are superconducting. The magnetic susceptibility of Pd/sub 2/TmSn and Pd/sub 2/YbSn deviates from the Curie-Weiss behavior at low temperatures indicating that crystalline electric field effects are appreciable. Analysis of the magnetic susceptibility data in terms of crystalline electric fields shows that the ground state of the Tm/sup 3 +/ ion is nonmagnetic which, therefore, does not affect the superconducting state. The susceptibility of Yb/sup 3 +/ ions at low temperatures is also reduced from the free-ion value due to the crystalline electric field interaction. The Tb- and Dy-containing compounds order antiferromagnetically with Neel temperatures of 9 and 15 K, respectively, while Er- and Ho-containing compounds are paramagnetic down to 1.4 K. The hyperfine field at the Sn site in Pd/sub 2/TbSn is about 50 kOe but is only about 10 kOe in Pd/sub 2/DySn at 4.2 K.

• Research Organization: Materials Science and Technology Division, Argonne National Laboratory, Argonne, Illinois 60439
• OSTI ID: 5790745
• Journal Information: Phys. Rev. B: Condens. Matter; (United States), Vol. 31:11
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
HEUSLER ALLOYS
MAGNETIC SUSCEPTIBILITY
PALLADIUM ALLOYS
RARE EARTH ALLOYS
TIN 119
MOESSBAUER EFFECT
TIN ALLOYS
CRYSTAL FIELD
CURIE-WEISS LAW
SAMPLE PREPARATION
SUPERCONDUCTIVITY
TERNARY ALLOY SYSTEMS
VALENCE
ALLOY SYSTEMS
ALLOYS
ALUMINIUM ALLOYS
COPPER ALLOYS
COPPER BASE ALLOYS
DAYS LIVING RADIOISOTOPES
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EVEN-ODD NUCLEI
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
MAGNETIC PROPERTIES
MANGANESE ALLOYS
NUCLEI
PHYSICAL PROPERTIES
PLATINUM METAL ALLOYS
RADIOISOTOPES
STABLE ISOTOPES
TIN ISOTOPES
360104* - Metals & Alloys- Physical Properties