Flame ionization detector response factors for compound classes in quantitative analysis of complex organic mixtures
Flame Ionization Detector (FID) response factors for 59 organic compounds were determined on GC using a WCOT column and cool on-column injection. Observed responses gave average response factors characteristic of each compound class. On the basis of multiple determinations, the mean response factor of 16 alkanes was determined to be 14.53 area counts/ng with a relative standard deviation of 1.4% and that of 22 polycyclic aromatic hydrocarbon standards was 13.47 area counts/ng with a relative standard deviation of 5.7%. Limited studies on oxy-PAH and nitro-PAH indicate that these compounds also exhibit characteristic FID response factors. These experimental results facilitate the quantitative analysis of multicomponents in a complex organic mixture by reducing demand on the number of standard compounds.
- Research Organization:
- Univ. of Waterloo, Ontario
- OSTI ID:
- 5787154
- Journal Information:
- Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 56:12; ISSN ANCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400102 -- Chemical & Spectral Procedures
400104* -- Spectral Procedures-- (-1987)
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
ALKANES
AROMATICS
CHEMICAL ANALYSIS
CHROMATOGRAPHY
DATA
EXPERIMENTAL DATA
FLAME PHOTOMETRY
GAS CHROMATOGRAPHY
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOTOMETRY
POLYCYCLIC AROMATIC HYDROCARBONS
QUANTITATIVE CHEMICAL ANALYSIS
SEPARATION PROCESSES