Reaction of dimethyl hydrogen phosphite with acecyclone

Journal Article · Mon Jul 20 04:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5775040

Arbuzov, B A; Fuzhenkova, A V; Tyryshkin, N I

In the presence of bases acecyclone reacts with dimethyl hydrogen phosphite with the formation of gamma-keto phosphonates with conjugated and unconjugated structures, and also an enol phosphate, a product containing a bond between oxygen of the cyclone and phosphorus. In the absence of bases, as well as the beta-keto phosphonate, gamma-keto phosphonates of cis and trans structure are formed; they are products of the 1,4 addition of dimethyl hydrogen phosphite to the conjugated fragment C=C-C=O of the cyclone. The compositions of the reaction mixture were determined by IR and NMR spectroscopy and TLC. Full-scale analysis of chemical shifts and spin-spin coupling constants was performed.

• Research Organization: A. M. Butlerov Chemistry Research Institute, USSR
• OSTI ID: 5775040
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
CHROMATOGRAPHY
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
KETONES
MELTING POINTS
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHOROUS ACID
PHYSICAL PROPERTIES
SEPARATION PROCESSES
SPECTRA
THERMODYNAMIC PROPERTIES
THIN-LAYER CHROMATOGRAPHY
TRANSITION TEMPERATURE