X-ray diffraction study of fullerene soot

Journal Article · Thu Jul 15 00:00:00 EDT 1993 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100130a004· OSTI ID:5771308

Scanlon, J C ^[1]; Ebert, L B ^[2]

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1. Exxon Corporate Research Lab., Annandale, NJ (United States)
2. Univ. of Chicago, IL (United States)

The X-ray diffraction pattern of pure buckminsterfullerene (C[sub 60]) is compared to that of exhaustively toluene-extracted fullerene soot. Both show diffraction lines which may be indexed to the 1.420 [+-] 0.005 nm cubic lattice of C[sub 60]. Additionally, the extracted fullerene soot shows diffraction peaks which may be indexed as the (002), (004), (100), (110), and (112) peaks of a planar benzenoid lattice. The coefficients of thermal expansion for the (311) peak of the C[sub 60] lattice and the (002) peak of the planar benzenoid lattice are both 3 [times] 10[sup [minus]5] [degree]C[sup [minus]1], which is the value of the (002) peak of graphite. Both phases of the extracted fullerene soot change on exposure to air at 600[degree]C: the C[sub 60] phase vanishes, and the in-plane component of the benzenoid phase grows. 22 refs., 3 figs.

• OSTI ID: 5771308
• Journal Information: Journal of Physical Chemistry; (United States), Journal Name: Journal of Physical Chemistry; (United States) Vol. 97:28; ISSN JPCHAX; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
ALKYLATED AROMATICS
AROMATICS
CARBON
COHERENT SCATTERING
DIFFRACTION
ELEMENTS
EXTRACTION
FULLERENES
HYDROCARBONS
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
NONMETALS
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
RESONANCE
SCATTERING
SEPARATION PROCESSES
SOOT
TOLUENE
X-RAY DIFFRACTION