Chemistry of sulfur in char and the implications for hydrogasification/hydrodesulfurization. [Ph. D. thesis]

Technical Report · Sat Sep 01 04:00:00 EDT 1979

DOI:https://doi.org/10.2172/5768682· OSTI ID:5768682

McIver, A. E.

Experimental results, which elucidate the factors which govern the equilibrium distribution of sulfur between organic sulfur in char and gaseous hydrogen sulfide, are presented. These experiments were conducted at between 1200 and 1600/sup 0/F, for values of the ratio (P/sub H/sub 2/S//P/sub H/sub 2//) ranging from 1 to 100, atmospheric pressure and for several chars. The rank of the parent coals from which these chars were derived ranged from lignite to anthracite. It is shown that the partial pressure ratio (P/sub H/sub 2/S//P/sub H/sub 2//) is the pressure-dependent parameter which governs the extent of char sulfidation. It is also shown that the extent of char sulfidation is not uniquely dependent upon char surface area, but decreases with increasing rank of the char, and the rank of the coal from which the char is derived. Char sulfidation is shown to be a reversible process. The kinetics of char desulfurization are shown to be a function of the physiochemical history of the char - i.e., char desulfurization is a path-dependent process. The analogy between the chemistries of oxygen and sulfur in char are explored, and the implications for coal sulfur management are outlined.

• Research Organization: Carnegie-Mellon Univ., Pittsburgh, PA (USA)
• OSTI ID: 5768682
• Report Number(s): FE-2449-9
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010400* -- Coal
Lignite
& Peat-- Processing
CHALCOGENIDES
CHARS
CHEMICAL REACTIONS
CHEMISTRY
COAL RANK
COAL RESERVES
CRYOGENIC FLUIDS
DESULFURIZATION
ELEMENTS
FLUIDS
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
HYDROGENATION
NONMETALS
NORTH AMERICA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN
PRESSURE DEPENDENCE
PYROLYSIS PRODUCTS
RESERVES
RESOURCES
SULFIDATION
SULFIDES
SULFUR
SULFUR COMPOUNDS
USA