Infrared/visible/ultraviolet spectroscopic detection of one-electron- and two-electron-reduction products of fac-CIR(CO)/sub 3/(4bzpy)/sub 2/ (4bzpy = 4-benzoylpyridine)

Journal Article · Wed Nov 16 00:00:00 EST 1988 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00296a051· OSTI ID:5761865

Shu, C F; Wrighton, M S

The results of a spectrochemical investigation of (fac-ClRe(CO)/sub 3/(4bzpy)/sub 2/) (4bzpy = 4-benzoylpyridine) concerning the nature of the products from one- and two-electron reduction of the complex are reported. The ir and uv/visible spectra of the one- and two-electron reduction products are compared. The spectral and electrochemical data obtained are uniformly consistent with the conclusion that the reduced metal complex has the electron(s) localized on the 4bzpy ligand(s). 14 refs., 2 figs., 1 tab.

• Research Organization: Massachusetts Institute of Technology, Cambridge (USA)
• OSTI ID: 5761865
• Journal Information: Inorg. Chem.; (United States), Vol. 27:23
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
ELECTROCHEMISTRY
CHLORINE COMPOUNDS
PYRIDINES
RHENIUM COMPLEXES
EXPERIMENTAL DATA
INFRARED SPECTRA
ULTRAVIOLET SPECTRA
VISIBLE SPECTRA
AZINES
CHEMISTRY
COMPLEXES
DATA
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation