Adsorption of certain oxygen-, nitrogen-, and sulfur-containing molecules and ions on copper and silver electrodes
Journal Article
·
· Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:5760547
The behavior of individual water, ethylenediamine, monoethanolamine, and thiourea molecules and of thiocyanate and cyanide ions on copper and silver electrodes was examined by the quantum-chemical method of CNDO/2 (complete neglect of differential overlap). Energy, structure, and charge characteristics were obtained for these molecules and ions in the adsorbed state. It was concluded that copper is more hydrophilic than silver, and an estimate was given for the potential of zero charge of the copper electrode. For the sulfur-containing surfactants, adsorption is suggested to be dissociative in character.
- Research Organization:
- S.M. Kirov Chemical Engineering Institute, Kazan, USSR
- OSTI ID:
- 5760547
- Journal Information:
- Sov. Electrochem. (Engl. Transl.); (United States), Vol. 22:7; Other Information: Translated from Elektrokhimiya; 22: No. 7, 897-902(Jul 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
AMINES
ADSORPTION
ATOMIC MODELS
QUANTUM MECHANICS
COPPER
SORPTIVE PROPERTIES
CYANIDES
SILVER
THIOCYANATES
THIOUREA
WATER
CHARGE DISTRIBUTION
DENSITY MATRIX
ELECTROCHEMISTRY
ELECTRODES
ELECTRON DENSITY
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
ELECTROSTATICS
FERMI LEVEL
POLYATOMIC MOLECULES
POTENTIALS
SLATER METHOD
SURFACTANTS
ANTITHYROID DRUGS
CARBONIC ACID DERIVATIVES
CHEMISTRY
DRUGS
ELEMENTS
ENERGY LEVELS
HORMONE ANTAGONISTS
HYDROGEN COMPOUNDS
MATHEMATICAL MODELS
MATRICES
MECHANICS
METALS
MOLECULES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
SORPTION
SURFACE PROPERTIES
THIOUREAS
TRANSITION ELEMENTS
400400* - Electrochemistry
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
AMINES
ADSORPTION
ATOMIC MODELS
QUANTUM MECHANICS
COPPER
SORPTIVE PROPERTIES
CYANIDES
SILVER
THIOCYANATES
THIOUREA
WATER
CHARGE DISTRIBUTION
DENSITY MATRIX
ELECTROCHEMISTRY
ELECTRODES
ELECTRON DENSITY
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
ELECTROSTATICS
FERMI LEVEL
POLYATOMIC MOLECULES
POTENTIALS
SLATER METHOD
SURFACTANTS
ANTITHYROID DRUGS
CARBONIC ACID DERIVATIVES
CHEMISTRY
DRUGS
ELEMENTS
ENERGY LEVELS
HORMONE ANTAGONISTS
HYDROGEN COMPOUNDS
MATHEMATICAL MODELS
MATRICES
MECHANICS
METALS
MOLECULES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
SORPTION
SURFACE PROPERTIES
THIOUREAS
TRANSITION ELEMENTS
400400* - Electrochemistry
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory