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PAS determination of the vacancy formation enthalpy in tungsten

Conference ·
OSTI ID:5757142
A measurement of the vacancy formation enthalpy in 99.999 wt % pure tungsten under thermal equilibrium conditions was made using the positron anihilation spectroscopy (PAS) Doppler-broadening technique. Temperatures were measured by optical pyrometry, with calibrations against a W(Re) thermocouple, the tantalum melting point, and the power delivered to the sample. A trapping-model analysis of the PAS data from the temperature range 300 to 3633 K yielded a vacancy formation enthalpy of 3.76 +- 0.39 eV. Comparisons are made between the present result and the other available results on vacancy formation in tungsten.
Research Organization:
Argonne National Lab., IL (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
5757142
Report Number(s):
CONF-850169-9; ON: DE85010283
Country of Publication:
United States
Language:
English