Reactions with molybdenum atoms
Thesis/Dissertation
·
OSTI ID:5755370
The formation and reactions of (eta/sup 6/-arene)/sub 2/Mo(0), (eta/sup 6/-arene(eta/sup 5/-cyclopentadianyl)molybdenum(I) and (eta/sup 6/-arene)(eta/sup 5/-cyclopentadienyl)molybdenum(II) hydrides were examined. The formation of sandwich compounds of molybdenum by metal atoms was studied by the use of relative rates. The relative rates of reactions of Mo atoms with arene mixtures at approximately -170/sup 0/C are spaced over the small overall range of 3.7 for the following arenes: toluene, t-butylbenzene, o-xylene, benzotrifluoride, N-N-dimethylaniline, fluorobenzene, methyl benzoate and anisole. The photochemical behavior of (eta/sup 6/-C/sub 6/H/sub 5/N(CH/sub 3/)/sub 2/)(eta/sup 5/-C/sub 5/H/sub 5/)MoH was examined. Photolysis of the hydride produced hydrogen and a 17 electron compound, (eta/sup 6/-C/sub 6/H/sub 5/N(CH/sub 2/)/sub 2/)(eta/sup 5/-C/sub 5/H/sub 5/)Mo. Experiments indicated that the hydrogen was produced by a bimolecular mechanism instead of intramolecular elimination of H atom abstraction from the solvent mechanisms.
- Research Organization:
- Pennsylvania State Univ., University Park (USA)
- OSTI ID:
- 5755370
- Country of Publication:
- United States
- Language:
- English
Similar Records
High-precision neutron diffraction investigation of the prototype biscyclopentadienyl transition metal hydride (eta/sup 5/-C/sub 5/H/sub 5/)/sub 2/MoH/sub 2/ and resolution of the structure in terms of modern bonding theory
Direct observation of. eta. sup 2 -arene complexes of ((C sub 5 Me sub 5 )Rh(PMe sub 3 ))
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
Journal Article
·
Wed Nov 30 23:00:00 EST 1977
· Inorg. Chem.; (United States)
·
OSTI ID:5184414
Direct observation of. eta. sup 2 -arene complexes of ((C sub 5 Me sub 5 )Rh(PMe sub 3 ))
Journal Article
·
Sat Dec 31 23:00:00 EST 1988
· Journal of the American Chemical Society; (United States)
·
OSTI ID:7039040
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
Journal Article
·
Tue Nov 03 23:00:00 EST 1981
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5845105
Related Subjects
36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400500 -- Photochemistry
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
EXPERIMENTAL DATA
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
KINETICS
MOLYBDENUM COMPOUNDS
MOLYBDENUM HYDRIDES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400500 -- Photochemistry
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
EXPERIMENTAL DATA
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
KINETICS
MOLYBDENUM COMPOUNDS
MOLYBDENUM HYDRIDES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS