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Orbital magnetism of singlet large bipolarons

Journal Article · · Physical Review, B: Condensed Matter; (USA)
 [1]
  1. Sandia National Laboratories, Albuquerque, New Mexico 87185-5800 (US)

Despite having no spin magnetism, a singlet large bipolaron in an anisotropic environment has a large anisotropic Van Vleck orbital paramagnetism. With the disklike large-bipolaron morphology envisioned for layered structures, the induced moment is aligned within the planes. The paramagnetic susceptibility and magnetic excitations of large bipolarons are suppressed in the condensate of interacting large bipolarons. Thus, carrier-related shifts of NMR frequencies and spin-lattice relaxation rates progressively fall as the temperature is lowered below {ital T}{sub {ital c}}.

DOE Contract Number:
AC04-76DP00789
OSTI ID:
5751154
Journal Information:
Physical Review, B: Condensed Matter; (USA), Journal Name: Physical Review, B: Condensed Matter; (USA) Vol. 43:4; ISSN PRBMD; ISSN 0163-1829
Country of Publication:
United States
Language:
English