Kinetics of the reverse Deacon reaction

Technical Report · Thu Oct 01 04:00:00 EDT 1981

OSTI ID:5747433

Nanda, A K

The reverse Deacon reaction Cl/sub 2/ + H/sub 2/O ..-->.. 2HCl + 1/2 O/sub 2/ is considered one of the most important steps in thermochemical water-splitting processes, for production of hydrogen from water. An investigation was made of the kinetics of the chlorination of water vapor at high temperatures. An eleven-pass glass reactor 4 mm ID and 511 mm long was used. Stimulus-response experiments showed the reactor could be analyzed by plug flow procedures. The rate expression for the reverse Deacon reaction was developed from the experimental data at 879/sup 0/K. Varying the partial pressures of the reactants, the rate data were collected, and these results were synthesized to formulate the rate law. The rate expression was verified by the integral approach and the results were extended to two other temperatures, 777 and 983/sup 0/K. The parameters of the rate expression were obtained by means of a linear-least-square fit. The frequency factor and activation energy were determined for the reverse Deacon reaction. An attempt was made to verify these parameters with the theoretical values from collision theory and activated complex theory. A mechanism consistent with one of the limiting conditions was postulated. A statistical study was also made to reveal the effects of the flow rates of the reactants and temperature on conversion of chlorine.

• Research Organization: Ames Lab., IA (USA)
• DOE Contract Number: W-7405-ENG-82
• OSTI ID: 5747433
• Report Number(s): IS-T-978; ON: DE82005621
• Country of Publication: United States
• Language: English

Related Subjects

08 HYDROGEN
080102* -- Hydrogen-- Production-- Thermochemical Processes
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATION
CHLORINE
ELEMENTS
FLUIDS
GASES
HALOGENATION
HALOGENS
HIGH TEMPERATURE
HYDROGEN PRODUCTION
KINETICS
NONMETALS
REACTION KINETICS
THERMOCHEMICAL PROCESSES
VAPORS
WATER VAPOR