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Study of complex oxides with the composition La/sub 2/3-x/Li/sub 3x/TiO/sub 3/

Journal Article · · Inorg. Mater. (Engl. Transl.); (United States)
OSTI ID:5740776
Oxides with the composition La/sub 2/3-x/Li/sub 3x/TiO/sub 3/ have the perovskite structure in a wide range of values of x. Lanthanum ions, which satisfy the requirements imposed on the ions of sublattice A, make the main contribution to the formation of the perovskite structure. Lithium ions, which reduce the number of vacancies, stabilize the structure. As lithium is substituted for lanthanum, the system changes from rhombic to tetragonal. Investigation of the electrical conductivity of the complex oxides La/sub 2/3-x/La/sub 3x/TiO/sub 3/ revealed high cationic conductivity, owing to the motion of lithium ions. The electrical conductivity of La/sub 2/3-x/Li/sub 3x/TiO/sub 3/ is characterized by the properties corresponding to superionic conductors.
OSTI ID:
5740776
Journal Information:
Inorg. Mater. (Engl. Transl.); (United States), Journal Name: Inorg. Mater. (Engl. Transl.); (United States) Vol. 23:3; ISSN INOMA
Country of Publication:
United States
Language:
English

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