Kinetics of the reaction of Cl and ClNO and ClNO/sub 2/ and the photochemistry of ClNO/sub 2/
Journal Article
·
· J. Phys. Chem.; (United States)
The room temperature rate constants for the reactions Cl + ClNO and Cl + ClNO/sub 2/ have been measured by the method of laser flash photolysis/resonance fluorescence. The rate constants obtained are (k/sub 2/ +- 2sigma) = (1.65 +- 0.32) x 10/sup -11/ cm/sup 3/ s/sup -1/ and k/sub 4/ = (5.50 +- 0.75) x 10/sup -12/ cm/sup 3/ s/sup -1/. The absorption spectrum of ClNO/sub 2/ was measured in the region 270 to 370 nm and the photodissociation channels ClNO/sub 2/ + hv ..-->.. Cl + NO/sub 2/ and ClNO/sub 2/ + hv ..-->.. ClNO + O were investigated by resonance fluorescence detection of Cl or O atoms. The quantum yields derived are phi/sub Cl/ = 0.93 +- 0.15 and phi/sub 0/ < 0.02.
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 5739281
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 85:25; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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·
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ABSORPTION SPECTRA
CHEMICAL REACTION KINETICS
CHEMISTRY
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
DATA
ELEMENTS
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HALOGENS
INFORMATION
KINETICS
NITROGEN COMPOUNDS
NONMETALS
NUMERICAL DATA
PHOTOCHEMISTRY
REACTION KINETICS
SPECTRA
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ABSORPTION SPECTRA
CHEMICAL REACTION KINETICS
CHEMISTRY
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
DATA
ELEMENTS
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HALOGENS
INFORMATION
KINETICS
NITROGEN COMPOUNDS
NONMETALS
NUMERICAL DATA
PHOTOCHEMISTRY
REACTION KINETICS
SPECTRA