ESR-ENDOR study of. cap alpha. -D-glucopyranose single crystals x irradiated at 12 and 77/sup 0/K

Journal Article · Thu Oct 04 04:00:00 EDT 1979 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100483a020· OSTI ID:5738013

Madden, K P; Bernhard, W A

Single crystals of anhydrous ..cap alpha..-D-glucopyranose x irradiated at 12 and 77/sup 0/K contain four free-radical species: two secondary alkoxy radicals centered at O-2, a primary hydroxyalkyl radical centered at C-6, and a secondary hydroxyalkyl radical centered at C-3. Structural considerations are discussed, and the radicals compared with four radicals found in single crystals of ..cap alpha..-D-glucopyranoside x irradiated under similar conditions. 4 figures, 3 tables.

• Research Organization: Univ. of Rochester, NY
• OSTI ID: 5738013
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 83:20; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALDEHYDES
ALKOXY RADICALS
CARBOHYDRATES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
GLUCOSE
HEXOSES
IONIZING RADIATIONS
MAGNETIC RESONANCE
MONOCRYSTALS
MONOSACCHARIDES
ORGANIC COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RESONANCE
SACCHARIDES
STRUCTURAL CHEMICAL ANALYSIS
ULTRALOW TEMPERATURE
VERY LOW TEMPERATURE
X RADIATION