A planar oxocuprate(II) array via heterometallic alkoxide chemistry

Journal Article · Wed Dec 19 04:00:00 EST 1990 · Journal of the American Chemical Society; (United States)

DOI:https://doi.org/10.1021/ja00182a023· OSTI ID:5737767

Samuels, J A; Vaarttra, B A; Huffman, J C; Trojan, K L; Hatfield, W E; Caulton, K G ^[1]

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1. Indiana Univ., Bloomington (United States) Univ. of North Carolina, Chapel Hill (United States)

Application of the molecular precursor method to the synthesis of copper-based high-temperature superconductors rests on the authors ability to produce copper containing heterometallic alkoxides. They have reported recently on the chemistry of the anion Zr{sub 2}-(O{sup i}Pr){sub 9}{sup {minus}}, which is related to recent reports by the group of Mehrotra. They report here their investigation of the coupling of this and related anions to CuCl{sub 2} of relevance to hydrolytic routes to copper/oxo superconductors.

• DOE Contract Number: FG02-88ER13906
• OSTI ID: 5737767
• Journal Information: Journal of the American Chemical Society; (United States), Journal Name: Journal of the American Chemical Society; (United States) Vol. 112:26; ISSN 0002-7863; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
665411 -- Basic Superconductivity Studies-- (1992-)
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ABSORPTION SPECTROSCOPY
ALKOXIDES
CARBON 13
CARBON ISOTOPES
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL REACTIONS
COMPLEXES
COPPER COMPLEXES
DECOMPOSITION
EVEN-ODD NUCLEI
HIGH-TC SUPERCONDUCTORS
HYDROGEN 1
HYDROGEN ISOTOPES
HYDROLYSIS
INFRARED SPECTRA
IONS
ISOTOPES
LIGHT NUCLEI
LYSIS
MAGNETIC PROPERTIES
MAGNETIC RESONANCE
MAGNETIC SUSCEPTIBILITY
MATHEMATICAL MODELS
MOLECULAR MODELS
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ODD-EVEN NUCLEI
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RESONANCE
SOLVOLYSIS
SPECTRA
SPECTROSCOPY
STABLE ISOTOPES
SUPERCONDUCTORS
SYNTHESIS
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE
TEMPERATURE RANGE 0013-0065 K
TEMPERATURE RANGE 0065-0273 K
TEMPERATURE RANGE 0273-0400 K
TRANSITION ELEMENT COMPLEXES
ZIRCONIUM COMPLEXES