Kinetics of reaction of cyclopentadiene with sodium
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5736904
The kinetics of the topochemical reaction of cyclopentadiene with metallic sodium were studied in a toluene medium. It was found that the observed rate of the first-order reaction is proportional to the surface of sodium and the cyclopentadiene concentration. The values of the energy of activation and reaction-rate constants are: E = 31 kJ/mole; k = 7.4 x 10/sup -4/ liter/m/sup 2/ x sec at 40/sup 0/C.
- Research Organization:
- M. V. Lomonosov Institute of Fine Chemical Technology, Moscow, USSR
- OSTI ID:
- 5736904
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:1; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METALS
ALKENES
ALKYLATED AROMATICS
AROMATICS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CYCLOALKENES
CYCLOPENTADIENE
DIENES
ELEMENTS
ENERGY
EQUATIONS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
KINETIC EQUATIONS
KINETICS
METALS
OPTIMIZATION
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
POLYENES
QUANTITY RATIO
REACTION KINETICS
SODIUM
SOLVATION
SOLVENTS
SURFACE AREA
SURFACE PROPERTIES
TOLUENE
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METALS
ALKENES
ALKYLATED AROMATICS
AROMATICS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CYCLOALKENES
CYCLOPENTADIENE
DIENES
ELEMENTS
ENERGY
EQUATIONS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
KINETIC EQUATIONS
KINETICS
METALS
OPTIMIZATION
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
POLYENES
QUANTITY RATIO
REACTION KINETICS
SODIUM
SOLVATION
SOLVENTS
SURFACE AREA
SURFACE PROPERTIES
TOLUENE