/sup 35/Cl NQR spectra of complexes of tetrachlorostannane with substituted benzoyl chlorides

Journal Article · Fri May 01 00:00:00 EDT 1987 · J. Struct. Chem. (Engl. Transl.); (United States)

OSTI ID:5736356

Feshin, V P; Dogushin, G V; Lazarev, I M; Voronkov, M G; Feshina, E V

/sup 35/Cl NQR spectra of mixtures of SnCl/sub 4/ with 2-, 3- and 4-XC/sub 6/H/sub 4/COCl were obtained. The electronic and steric structure of the complexes obtained was established. Their formation and structure depend on the nature of substituents X. Complexes with a trigonal-bipyramidal structure are formed with the participation of the carbonyl oxygen atom of the ligand as an electron-donor-center, and complexes with trans-octahedral structure, with the participation of the sulfur atom of the X = CH/sub 3/S substituent.

• Research Organization: Irkutsk Institute of Organic Chemistry, USSR
• OSTI ID: 5736356
• Journal Information: J. Struct. Chem. (Engl. Transl.); (United States), Journal Name: J. Struct. Chem. (Engl. Transl.); (United States) Vol. 27:6; ISSN JSTCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
BINDING ENERGY
CHARGE DISTRIBUTION
CHLORIDES
CHLORINE 35
CHLORINE COMPOUNDS
CHLORINE ISOTOPES
COMPLEXES
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
HALIDES
HALOGEN COMPOUNDS
HYPERFINE STRUCTURE
ISOTOPES
LEPTONS
LIGANDS
LIGHT NUCLEI
LINE WIDTHS
MULTIPLETS
NUCLEAR QUADRUPOLE RESONANCE
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
RESONANCE
SPECTRAL SHIFT
STABLE ISOTOPES
STEREOCHEMISTRY
TIN CHLORIDES
TIN COMPLEXES
TIN COMPOUNDS
TIN HALIDES
VALENCE