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Kinetics of reaction of acetyl iodide with methyl acetate

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5735856
; ;
The kinetics of the reaction of acetyl iodide with methyl acetate were studied. It was found that the reaction proceeds only with acid catalysis by the AAc/sub 2/ mechanism. Catalysis by hydrohalides (HI, HCl) is accompanied by consumption of the catalyst due to reaction with acetic anhydride.
Research Organization:
D. I. Mendeleev Chemical Engineering Institute, Moscow, USSR
OSTI ID:
5735856
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:4; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETIC ACID
ACETIC ACID ESTERS
ACTIVATION ENERGY
ANHYDRIDES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLATION
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
ENERGY
EQUATIONS
ESTERS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIODIC ACID
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INORGANIC ACIDS
IODINATED ALIPHATIC HYDROCARBONS
IODINE COMPOUNDS
KINETIC EQUATIONS
KINETICS
METHYL ACETATE
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROMOTERS
REACTION KINETICS
TIME DEPENDENCE