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Transport properties of boron carbide

Journal Article · · AIP Conf. Proc.; (United States)
DOI:https://doi.org/10.1063/1.35596· OSTI ID:5727768
Electrical conductivity, Seebeck-coefficient, and Hall-effect measurements have been made on single-phase microcrystalline boron carbides, B/sub x/C, in the compositional range 4< or =x< or =9 between liq. N/sub 2/ temperature and 2273 K. Thermal cycling effects are also discussed. In addition, conductivity and Seebeck coefficient measurements are reported on a large-grain polycrystal. The results tend to confirm that boron carbide is a degenerate semiconductor in which the predominant conduction mechanism is small-bipolaron hopping between carbon atoms at energetically inequivalent sites in highly disordered structures.
Research Organization:
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109
OSTI ID:
5727768
Report Number(s):
CONF-850786-
Journal Information:
AIP Conf. Proc.; (United States), Journal Name: AIP Conf. Proc.; (United States) Vol. 140:1; ISSN APCPC
Country of Publication:
United States
Language:
English