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Time-dependent Hartree-Fock theory and the Rayleigh-Ritz principle

Journal Article · · Phys. Rev., C; (United States)

The trial function Psi in the Rayleigh-Ritz variational principle, delta=0, is restricted to a continuous superposition of Slater determinants Phi (t), Psi=..integral..dt f (t) Phi (t). The variation delta is performed upon the path )Phi (t) ). It is found that time-dependent Hartree-Fock solutions Phi (t) are optimal choices for making the Rayleigh-Ritz functional stationary.

Research Organization:
Commisariat a l'Energie Atomique, Division de la Physique, Service de Physique Theorique, Centre d'Etudes Nucleaire de Saclay, Boite Postale No. 2, 91190 Gif-sur-Yvette, France
OSTI ID:
5727043
Journal Information:
Phys. Rev., C; (United States), Journal Name: Phys. Rev., C; (United States) Vol. 21:1; ISSN PRVCA
Country of Publication:
United States
Language:
English