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Invert emulsion drilling fluid comprising oligamide composition

Patent ·
OSTI ID:5717495
A water-in-oil emulsion fluid is described for use in the drilling, completion or workover of a subterranean well comprising: (1) a liquid hydrocarbon base; (2) an aqueous phase; and (3) a surfactant, the surfactant comprising: an oligamide prepared by reacting from between about 20 mole percent and about 35 mole percent of a polyalkylene polyamine having two or more alkylene groups separated by nitrogen atoms, and from between about 30 mole percent and about 70 mole percent of a fatty acid having from between about 6 to about 20 carbon atoms therein. The polyamine and fatty acid is reacted to form a diamide intermediate product, the diamide intermediate product being further reacted with from between about 15 mole percent to about 35 mole percent of a tricarboxylic acid selected from citric acid and trimellitic acid to form an oligamide. The surfactant, when diluted to 70 percent w/w concentration with a suitable solvent, having an acid value from about 26 to about 46. The surfactant has a total amine value from between about 10 to about 30, the drilling fluid produced with the surfactant having an ES/sub 3/ of at least about 400 volts, and an ES/sub 5/ greater than the ES/sub 4/ thereof, the ES/sub 5/ being greater than about 1,000 volts.
Assignee:
Milchem, Inc., Houston, TX
Patent Number(s):
US 4575428
OSTI ID:
5717495
Country of Publication:
United States
Language:
English