Measurement of xenon distribution statistics in Na-A zeolite cavities

Journal Article · Sun Feb 03 23:00:00 EST 1991 · Physical Review Letters; (USA)

DOI:https://doi.org/10.1103/PhysRevLett.66.580· OSTI ID:5711490

Chmelka, B F; Raftery, D; McCormick, A V; de Menorval, L C; Levine, R D; Pines, A ^[1]

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1. Lawrence Berkeley Laboratory, Berkeley, CA (USA). Materials Sciences Division University of California, Berkeley, CA (USA). Department of Chemistry

{sup 129}Xe NMR spectroscopy has been used to probe directly the distribution of xenon atoms confined in atomic-size Na-A zeolite cavities. For mean xenon occupancies less than about three Xe atoms per {alpha}-cage, the guest populations are well described by binomial statistics. At higher guest loadings the finite volumes of the xenon atoms become significant, as reflected by a fit of the experimental populations with a hypergeometric distribution. The data and hypergeometric analysis indicate a maximum occupancy of seven Xe atoms/cage. At the highest xenon loadings the experimental distribution is narrower than hypergeometric.

• DOE Contract Number: AC03-76SF00098
• OSTI ID: 5711490
• Journal Information: Physical Review Letters; (USA), Journal Name: Physical Review Letters; (USA) Vol. 66:5; ISSN PRLTA; ISSN 0031-9007
• Country of Publication: United States
• Language: English

Related Subjects

640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
656002* -- Condensed Matter Physics-- General Techniques in Condensed Matter-- (1987-)
74 ATOMIC AND MOLECULAR PHYSICS
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ALKALI METAL COMPOUNDS
CORRELATIONS
DATA
DAYS LIVING RADIOISOTOPES
DISTRIBUTION
ELEMENTS
EQUILIBRIUM
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
FLUIDS
GASES
HEATING
HIGH TEMPERATURE
INFORMATION
INORGANIC ION EXCHANGERS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ION EXCHANGE MATERIALS
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
MAGNETIC RESONANCE
MATERIALS
MATRIX ISOLATION
MEDIUM TEMPERATURE
MINERALS
MOLECULES
NONMETALS
NUCLEAR MAGNETIC RESONANCE
NUCLEI
NUMERICAL DATA
POROSITY
PRESSURE DEPENDENCE
PROBABILITY
PROBES
RADIOISOTOPES
RARE GASES
RESONANCE
SODIUM COMPOUNDS
STABLE ISOTOPES
TRAPPING
XENON
XENON 129
XENON ISOTOPES
ZEOLITES