Reactive infinite order sudden rate constants for F + H/sub 2/(v=0, j=0). -->. H + HF(v')

Journal Article · Thu Sep 01 04:00:00 EDT 1983 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100241a004· OSTI ID:5704303

Jellinek, J ^[1]; Baer, M; Kouri, D J

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1. Weizmann Inst. of Sciences, Rehovot, Israel

State-selected and total reactive rate constants for the F + H/sub 2/(v=0, j=0) ..-->.. HF(v = 1,2,3) + H reaction have been recalculated from the most recent reactive infinite order sudden (RIOS) approximation cross sections obtained with the l-average choice of anti l. Comparisons with classical trajectory and experimental results are made. The RIOS results, although larger than any others obtained with the Muckerman 5 (M5) potential, are still smaller than any of the experimental results. 3 figures.

• OSTI ID: 5704303
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 87:18; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
640304* -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
ATOMS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COLLISIONS
COMPARATIVE EVALUATIONS
CROSS SECTIONS
DATA
ELEMENTS
ENERGY-LEVEL TRANSITIONS
EXCITATION
FLUORINE
HALOGENS
HIGH TEMPERATURE
HYDROFLUORIC ACID
HYDROGEN
HYDROGEN COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
MEDIUM TEMPERATURE
MOLECULE COLLISIONS
MOLECULES
NONMETALS
NUMERICAL DATA
REACTION KINETICS
SUDDEN APPROXIMATION
TEMPERATURE DEPENDENCE
THEORETICAL DATA
YIELDS