Do your extractable TPH concentrations represent dissolved petroleum? An update on applied research
- Geomatrix Consultants, Inc., San Francisco, CA (United States)
Elevated concentrations of {open_quotes}dissolved-phase{close_quotes} extractable total petroleum hydrocarbons (TPH) in groundwater samples can be a significant impediment to site closure in states that regulate groundwater using TPH criteria. These analytical results are inconsistent with petroleum chemistry because of the relatively low water solubility of petroleum products. This paper presents an update of our research into the source of medium- to high-boiling TPH detections in groundwater samples and application of the results to multiple projects. This work follows from a 1995 publication in which positive interferences to the Method 8015M (GC-FID) TPH measurement by soluble, non-petroleum hydrocarbons resulting from intrinsic bioremediation or non-dissolved petroleum adhered to particulates was described. The 1995 paper was largely theoretical and focused on one case study. Since 1995, we have evaluated the source of TPH detections in groundwater at numerous petroleum sites and have demonstrated the significance of interferences to the Method 8015M measurement to the California regulatory community. Our work has shown conclusively that elevated concentrations of extractable TPH are not representative of dissolved petroleum constituents. We have shown that a sample cleanup prior to analysis using silica gel cleanup (to remove polar non-petroleum hydrocarbons) and/or laboratory filtration (to reduce petroleum-affected particulates) is required to overcome the false positives caused by interferences to the Method 8015M measurement.
- OSTI ID:
- 569982
- Report Number(s):
- CONF-971116-; TRN: 98:000778-0047
- Resource Relation:
- Conference: 1997 petroleum hydrocarbons and organic chemicals in ground water: prevention, detection, and remediation conference, Houston, TX (United States), 12-14 Nov 1997; Other Information: PBD: 1997; Related Information: Is Part Of Proceedings of the 1997 petroleum hydrocarbons & organic chemicals in ground water: Prevention, detection, and remediation; PB: 811 p.
- Country of Publication:
- United States
- Language:
- English
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