Reaction rates for thermal chlorine atoms with H/sub 2/S from 232 to 359 K by a radiochemical technique

Journal Article · Wed May 07 20:00:00 EDT 1986 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100401a002· OSTI ID:5699112

Lu, E C.C.; Iyer, R S; Rowland, F S

The relative rate constants for the gas-phase reactions of thermal chlorine atoms have been measured with H/sub 2/S, C/sub 2/H/sub 6/, and CH/sub 2/ = CHBr over the temperature range from 232 to 359 K by using radioactive /sup 38/Cl atoms. These data at a pressure of 4000 Torr of CClF/sub 3/ are consistent with a temperature-dependent rate constant of (10.5 +/- 0.4) x 10/sup -11/ cm/sup 3/ molecule/sup -1/ s/sup -1/, based on the consensus literature values for the reaction of Cl with C/sub 2/H/sub 6/. 15 references, 1 figure, 2 tables.

• Research Organization: Univ. of California, Irvine
• OSTI ID: 5699112
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 90:10; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
500100 -- Environment
Atmospheric-- Basic Studies-- (-1989)
54 ENVIRONMENTAL SCIENCES
640107 -- Astrophysics & Cosmology-- Planetary Phenomena
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHLORINE
CHLORINE 38
CHLORINE ISOTOPES
DATA
ELEMENTS
EXPERIMENTAL DATA
HALOGENS
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
INFORMATION
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
LIGHT NUCLEI
LOW TEMPERATURE
MEDIUM TEMPERATURE
MINUTES LIVING RADIOISOTOPES
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
QUANTITATIVE CHEMICAL ANALYSIS
RADIOCHEMICAL ANALYSIS
RADIOISOTOPES
REACTION KINETICS
SECONDS LIVING RADIOISOTOPES
SULFIDES
SULFUR COMPOUNDS
TEMPERATURE DEPENDENCE