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U.S. Department of Energy
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Sodium-sulfur cells with high conductivity glass electrolytes

Conference ·
OSTI ID:5697028
A study is under way to develop glasses in the soda-alumina-zirconia-silica system that have high conductivity for sodium ions. Sodium-conductivity and corrosion experiments indicate that the target resistivity of 100 ohm-cm at 300/sup 0/C can be achieved for glasses having satisfactory corrosion resistance for use in sodium-sulfur cells. The low resistivity makes possible a unique approach to cell design. Cells of 150 A-hr capacity were designed having 6-mm dia electrolytes and are expected to achieve a specific energy of up to 270 W-hr/kg. Others having 1.5-mm dia electrolytes are expected to attain a specific power of up to 2 or 3 kW/kg. Excellent heat removal can be provided for high-specific-power cells by short metallic paths from the center of the cell to the cooled cell wall. Reliability of the cell may be achieved by: (1) use of a protective tube around each electrolyte tube to protect against failure propagation and (2) the provision for automatic disconnection of a failed element by burnout of its current collector wire.
Research Organization:
Argonne National Lab., IL (USA); Cincinnati Univ., OH (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
5697028
Report Number(s):
CONF-850808-7; ON: DE85012371
Country of Publication:
United States
Language:
English

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