Stimulated Raman spectrum of the. nu. /sub 1/ fundamental of CD/sub 4/ in a molecular jet

Journal Article · Thu Feb 17 04:00:00 EST 1983 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100227a017· OSTI ID:5693822

Esherick, P ^[1]; Owyoung, A; Patterson, C W

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1. Sandia National Lab., Albuquerque, NM

Doppler-limited stimulated Raman spectra of the ..nu../sub 1/ fundamental of CD/sub 4/ have been obtained both at room temperature in a static cell and at approx.45 K in a molecular free-expansion jet. Spectral interferences due to overlapping hot-band transitions are significantly reduced in the molecular jet, thereby allowing an unambiquous assignment of the band origin at 2101.373 cm/sup -1/. Analysis of the spectrum and determination of the relevant spectral constants leads to the conclusion that the ..nu../sub 1/ band is strongly perturbed, probably by Coriolis interactions with the nearby ..nu../sub 2/ + ..nu../sub 4/ band.

• DOE Contract Number: AC04-76DP00789
• OSTI ID: 5693822
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 87:4; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
CORIOLIS FORCE
DEUTERIUM COMPOUNDS
DOPPLER EFFECT
HYDROCARBONS
HYDROGEN COMPOUNDS
JET MODEL
MATHEMATICAL MODELS
METHANE
ORGANIC COMPOUNDS
PARTICLE MODELS
RAMAN SPECTRA
SPECTRA
SPECTROSCOPY