Derivatization of the fullerene dications C{sub 60}{sup 2+} and C{sub 70}{sup 2+} by ion-molecule reactions in the gas phase

Journal Article · Wed Nov 04 04:00:00 EST 1992 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja00049a059· OSTI ID:569227

Petrie, S; Javahery, G; Wang, Jinru; Bohme, D K ^[1]

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1. York Univ., North York, Ontario (Canada)

This study focuses on the derivatization of the fullerene dications C{sub 60}{sup 2+} and C{sub 70}{sup 2+} by ion-molecule reactions in the gas phase. This was accomplished using a Selected-Ion Flow Tube (SIFT) apparatus. A model is also presented which relates the efficiency of adduct formation to the ionization energy, the size, and the degree of unsaturation of the molecules. 28 refs., 3 figs., 3 tabs.

• Sponsoring Organization: USDOE
• OSTI ID: 569227
• Journal Information: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 23 Vol. 114; ISSN JACSAT; ISSN 0002-7863
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
40 CHEMISTRY
ACTIVATION ENERGY
ADDUCTS
AMINES
CARBON
CATIONS
CHEMICAL BONDS
CHEMICAL PROPERTIES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DERIVATIZATION
FULLERENES
GAS ANALYSIS
HYDROCARBONS
ION-MOLECULE COLLISIONS
PHASE TRANSFORMATIONS
PHYSICAL PROPERTIES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS