Ion chromatography of organic carboxylic acids. Determination of monobasic carboxylic and hydroxy acids
An ion chromatographic method has been developed for the determination of monobasic carboxylic and hydroxy acids, as well as some of their chloroderivatives. The optimum eluent for the joint determination of monobasic carboxylic and hydroxy acids, fluoride and chloride ions is a 1 x 10/sup -4/ M solution of NaOH. The limit of detection of acids with this eluent is equal to (1.5-3.1) x 10/sup -3/ ..mu..g/ml. Inorganic anions (F/sup -/, Cl/sup -/, NO/sub 3//sup -/, and SO/sub 4//sup 2 -/), as well as dibasic carboxylic and hydroxy acids, do not interfere with the determination of monobasic carboxylic and hydroxy acids. The method has been used for the determination of lactic acid in gastric juice and that of formic, acetic, propionic, and butyric acids in water and condensate of thermoelectric power plants.
- Research Organization:
- Lomonosov Moscow State Univ., Moscow (Russian Federation)
- OSTI ID:
- 5690890
- Journal Information:
- J. Anal. Chem. USSR (Engl. Transl.); (United States), Vol. 41:1; Other Information: Translated from Zh. Anal. Khim.; 41: No. 1, 134-139(Jan 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
COOLANTS
ION EXCHANGE CHROMATOGRAPHY
HYDROXY ACIDS
MONOCARBOXYLIC ACIDS
THERMAL POWER PLANTS
CATIONS
CHLORINE COMPOUNDS
CONDENSATES
FLUORINE COMPOUNDS
ION EXCHANGE
MATERIALS TESTING
MONITORING
NITRATES
ORGANIC ION EXCHANGERS
ORGANIC SOLVENTS
QUANTITY RATIO
RESINS
SENSITIVITY
SODIUM HYDROXIDES
SOLVENT PROPERTIES
SULFATES
TIME DEPENDENCE
WATER POLLUTION
ALKALI METAL COMPOUNDS
CARBOXYLIC ACIDS
CHARGED PARTICLES
CHROMATOGRAPHY
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXIDES
ION EXCHANGE MATERIALS
IONS
MATERIALS
NITROGEN COMPOUNDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
POLLUTION
POLYMERS
POWER PLANTS
SEPARATION PROCESSES
SODIUM COMPOUNDS
SOLVENTS
SULFUR COMPOUNDS
TESTING
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