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Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109

Technical Report ·
DOI:https://doi.org/10.2172/568984· OSTI ID:568984
This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data.
Research Organization:
Pacific Northwest National Lab., Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
568984
Report Number(s):
PNNL--11777; ON: DE98051462; BR: 820201000
Country of Publication:
United States
Language:
English