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Inductively coupled plasma emission spectrometric detection of simulated high performance liquid chromatographic peaks

Journal Article · · Anal. Chem.; (United States)
DOI:https://doi.org/10.1021/ac50049a037· OSTI ID:5686292
; ;
Because of its multielement capability, element-specificity, and low detection limits, inductively coupled plasma optical emission spectrometry (ICP) is a very promising technique for the detection of specific elemental species separated by high performance liquid chromatography (HPLC). This paper evaluated ICP as a detector for HPLC peaks containing specific elements. Detection limits for a number of elements have been evaluated in terms of the minimum detectable concentration of the element at the chromatographic peak maximum. The elements studies were Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sb, Se, Sr, Ti, V, and Zn. In addition, ICP was compared with atomic absorption spectrometry for the detection of HPLC peaks composed of EDTA and NTA chelates of copper. Furthermore, ICP was compared to uv solution absorption for the detection of copper chelates. 6 figures, 4 tables.
Research Organization:
Univ. of Missouri, Columbia
OSTI ID:
5686292
Journal Information:
Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 51:13; ISSN ANCHA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
ABSORPTION SPECTROSCOPY
ALKALI METALS
ALKALINE EARTH METALS
ALUMINIUM
ANTIMONY
ARSENIC
BARIUM
BORON
CADMIUM
CALCIUM
CHEMICAL ANALYSIS
CHROMATOGRAPHY
CHROMIUM
COBALT
COPPER
COPPER COMPOUNDS
ELEMENTS
EMISSION SPECTROSCOPY
IRON
LEAD
LIQUID COLUMN CHROMATOGRAPHY
LITHIUM
MAGNESIUM
MANGANESE
METALS
MOLYBDENUM
NICKEL
NONMETALS
PHOSPHORUS
POTASSIUM
QUANTITATIVE CHEMICAL ANALYSIS
REFRACTORY METALS
SELENIUM
SEMIMETALS
SEPARATION PROCESSES
SODIUM
SPECTROSCOPY
STRONTIUM
TITANIUM
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
VANADIUM
ZINC