Calculation of the structure factor for a Pd/sub 1-c/Si/sub c/ melt in the long-wavelength limit from experimental data on the EMF of alloy formation

Journal Article · Sun Jun 01 00:00:00 EDT 1986 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:5684005

Vatolin, N A; Kobeleva, R M; Pastukhov, E A; Sidorov, N I

The authors investigate the x-ray diffraction long-wavelength limit and the concentration dependence of the structure factors - Bhatia-Thornton and Faber-Ziman among them - for a liquid palladium-silicon alloy based on the relationship between the structure factors and the excess Gibbs potential which takes into account the partial thermodynamic Gibbs potential, the electromotive force for alloy formation, the universal gas constant, the valence, the pressure, and the absolute temperature. Their results indicate that the palladium-silicon alloy belongs to a system category with strong chemical interaction between palladium and silicon.

• Research Organization: Institute of Metallurgy, Sverdlovsk, USSR
• OSTI ID: 5684005
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 285:4-6; Other Information: Translated from Dokl. Akad. Nauk SSSR; 285: No. 4, 915-918(Dec 1985)
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
PALLADIUM ALLOYS
ELECTROMOTIVE FORCE
STRUCTURE FACTORS
X-RAY DIFFRACTION
SILICON ALLOYS
X RADIATION
WAVELENGTHS
CRYSTAL STRUCTURE
FARADAY EFFECT
FORMATION FREE ENTHALPY
FORMATION HEAT
LIQUID METALS
POTENTIALS
QUANTITY RATIO
SCATTERING AMPLITUDES
VALENCE
ALLOYS
AMPLITUDES
COHERENT SCATTERING
DIFFRACTION
ELECTROMAGNETIC RADIATION
ELEMENTS
ENERGY
ENTHALPY
FLUIDS
FREE ENTHALPY
IONIZING RADIATIONS
LIQUIDS
METALS
PHYSICAL PROPERTIES
PLATINUM METAL ALLOYS
RADIATIONS
REACTION HEAT
SCATTERING
THERMODYNAMIC PROPERTIES
360102* - Metals & Alloys- Structure & Phase Studies
360104 - Metals & Alloys- Physical Properties