Polarity and stability of complexes of aluminum chloride with n-donors

Journal Article · Fri Jun 20 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5676980

Romm, I P; Moshchenok, S V; Ivanov, L P; Gur'yanova, E N; Gorbunov, A I

Aluminum chloride forms D x AlCl/sub 3/ complexes with amines, ethers, sulfides, and phosphines in benzene solution. The properties of the aluminum chloride complexes are in accord with the general relationships for the complexes of other aluminum and gallium halides and organometallic compounds with n-donors (-..delta..H/sub 1//sup c/ is linearly related to sigma* and ..mu../sub DA//er/sub DA/ values). The acceptor properties of AlCl/sub 3/ and AlBr/sub 3/ relative to n-donors are similar.

• Research Organization: L. Ya. Karpov Institute of Physical Chemistry, Moscow, USSR
• OSTI ID: 5676980
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:1; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALUMINIUM BROMIDES
ALUMINIUM CHLORIDES
ALUMINIUM COMPLEXES
ALUMINIUM COMPOUNDS
AMINES
AROMATICS
BENZENE
BINDING ENERGY
BROMIDES
BROMINE COMPOUNDS
CALORIMETRY
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DIPOLE MOMENTS
ELECTRON TRANSFER
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ENTHALPY
ETHERS
FERMIONS
FORMATION HEAT
GALLIUM COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
LEPTONS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
STABILITY
SULFIDES
SULFUR COMPOUNDS
THERMODYNAMIC PROPERTIES
THERMODYNAMICS
TITRATION
VALENCE