Structural peculiarities of isotope-substituted aqueous methanol solutions of the noble gases
Journal Article
·
· Dokl. Phys. Chem. (Engl. Transl.); (United States)
OSTI ID:5676505
In this work they studied the solubility of Ne, Ar, Kr, and Xe in a mixture of water and methanol of various degrees of isotope substitution (CH/sub 3/OH-H/sub 2/O, CD/sub 3/OH-H/sub 2/O, CH/sub 3/OD-D/sub 2/O, CD/sub 3/OD-D/sub 2/). The experimental data are presented in the form of solvomolar absorption coefficients A/sub sm, on the basis of which the isotope effect deltaA/sub sm/ (the difference of the solubility of the noble gas in the given deutero-substituted solvent and in a solvent with a different isotope substitution of the same composition) were calculated.
- Research Organization:
- Institute of the Chemistry of Nonaqueous Solutions, Ivanovo, USSR
- OSTI ID:
- 5676505
- Journal Information:
- Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 288:1-3; ISSN DKPCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400202* -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALCOHOLS
AQUEOUS SOLUTIONS
ARGON
CHEMICAL REACTIONS
DEUTERATION
DEUTERIUM COMPOUNDS
DISPERSIONS
ELEMENTS
FLUIDS
GASES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
ISOTOPE EFFECTS
ISOTOPIC EXCHANGE
KRYPTON
METHANOL
MIXTURES
MOLECULAR STRUCTURE
NEON
NONMETALS
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
RARE GASES
SOLUBILITY
SOLUTIONS
SOLVENT PROPERTIES
SOLVENTS
STRUCTURAL CHEMICAL ANALYSIS
XENON
400202* -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALCOHOLS
AQUEOUS SOLUTIONS
ARGON
CHEMICAL REACTIONS
DEUTERATION
DEUTERIUM COMPOUNDS
DISPERSIONS
ELEMENTS
FLUIDS
GASES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
ISOTOPE EFFECTS
ISOTOPIC EXCHANGE
KRYPTON
METHANOL
MIXTURES
MOLECULAR STRUCTURE
NEON
NONMETALS
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
RARE GASES
SOLUBILITY
SOLUTIONS
SOLVENT PROPERTIES
SOLVENTS
STRUCTURAL CHEMICAL ANALYSIS
XENON